Thats your problem. You are new at the game. Unless you are me, you will not start winning as soon as you pop in the game. Its extremely hard to do so and the only reason I won my first 12 games online was because I hit training mode with Wolverine/Sentinel/Akuma and tried to find some broken technology before anybody else could and I could show the world/SRK (Justin beat me too it. If only I had the game on the 14th… FUCK THE LEVELUP STREAM!!! LOL)
So my suggestion is to go to training mode and learn the combos, strats, resets, mix-ups, and everything else Mahvel and then after you are comfortable with everything, then go online and try it out.
Also, your teams… ewwww… lol.
If you like Wolverine and Chun-li, may I suggest a couple teams?
Wolverine (y)/Chun (y)/Sentinel (a) or Wesker (b)- I use to run this team to see the effect of Wolverine’s beserker slash into Chun’s legs. On hit, beserker slash knocks the opponent into her legs and you get a free combo. On hit, beserker charge knocks the opponent towards chun’s legs, they recieve chip and you get a free high/low/side2side mixup. Chun needs projectiles or a multi-hitting assist to cover her and also an OTG if you want pack a punch. So I put Sentinel and Wesker in as suggestions.
xxx/Sentinel (a)/Phoenix (b or a)- This is a true phoenix team. Why I say this? Because you can literally put ANY rushdown character in that first slot, and you will have a good team. Hands down. Chun-li will go great, because she can gain so much meter for Phoenix. So will Wolverine (look at Tokido)
There are more that I will list later.